TOILET BOWL CLEANER(LEMON)

·TOILET BOWL CLEANER

Chemical characterization
· Description: Mixture of the substances listed below with nonhazardous additions.
· Dangerous components:
5949-29-1 citric acid monohydrate 30.0%
497-19-8 sodium carbonate 28.0%
25155-30-0 sodium dodecylbenzenesulphonate, pure 20.0%
26172-55-4 5-chloro-2-methyl-2H-isothiazol-3-one 9.0%
15356-70-4 D-menthol 0.38%
5392-40-5 Citral 0.24%
78-70-6 Linalool 0.08%
· Non-dangerous components:
1934-21-0 trisodium 5-hydroxy-1-(4-sulphophenyl)-4-(4-sulphophenylazo)pyrazole-3-carboxylate 11.0%
93-92-5 1-phenylethyl acetate 0.82%
124-13-0 octanal 0.24%
112-31-2 decanal 0.18%
105-54-4 ethyl butyrate 0.06%
· Remark:
Octanal

· Remark:
Octanal (CAS No. 124-13-0)
Synonym: Caprylic aldehyde
Decanal (CAS No. 112-31-0)
Synonym: Decyl aldehyde
1-Phenylethyl acetate (CAS No. 93-92-5)
Synonym: Styrallyl acetate
Trisodium 4,5-dihydro-5-oxo-1-(4-sulfophenyl)-4-((4-sulfophenyl)azo)-1H-pyrazole-3-carboxylate (CAS No.
1934-21-0)
Synonym: 4,5-Dihydro-5-oxo-1-(4-sulfophenyl)-4-((4-sulfophenyl)azo)-1H-pyrazole-3-carboxylic acid,
trisodium salt

Hazards identification
· Hazard description:
Corrosive
Dangerous for the environment
· Information pertaining to particular dangers for man and environment:
The product has to be labelled due to the calculation procedure of international guideline.
Harmful by inhalation, in contact with skin and if swallowed.
Danger of cumulative effects.
Causes burns.
Irritating to respiratory system.
May cause sensitisation by skin contact.
Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
· Classification system:
The classification was made according to the latest editions of international substances lists, and expanded
upon from company and literature data.
· NFPA ratings (scale 0 – 4)
3
0
0
Health = 3
Fire = 0
Reactivity = 0
· HMIS-ratings (scale 0 – 4)
HEALTH
FIRE
REACTIVITY
3
0
0
Health = 3
Fire = 0
Reactivity = 0

First aid measures
· General information:
Immediately remove any clothing soiled by the product.
Symptoms of poisoning may even occur after several hours; therefore medical observation for at least 48
hours after the accident.
· After inhalation:
Supply fresh air and to be sure call for a doctor.
In case of unconsciousness place patient stably in side position for transportation.
· After skin contact: Immediately wash with water and soap and rinse thoroughly.
· After eye contact: Rinse opened eye for several minutes under running water. Then consult a doctor.
· After swallowing:
Immediately call a doctor.
Drink copious amounts of water and provide fresh air. Immediately call a doctor.

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Inform respective authorities in case of seepage into water course or sewage system.
Do not allow to enter sewers/ surface or ground water.
· Measures for cleaning/collecting:
Pick up mechanically.
Use neutralizing agent.
Dispose contaminated material as waste according to item 13.
Ensure adequate ventilation.
· Additional information: See Section 7 for information on safe handling.

7 Handling and storage
· Handling:
· Information for safe handling:
Ensure good ventilation/exhaustion at the workplace.
Prevent formation of dust.
· Information about protection against explosions and fires: Keep ignition sources away – Do not smoke.
· Storage:
· Requirements to be met by storerooms and receptacles:
Store in a cool location.
Protect from heat and direct sunlight.
· Information about storage in one common storage facility:
Do not store together with acids.
Store away from oxidizing agents.
· Further information about storage conditions:
Keep receptacle tightly sealed.
Protect from humidity and water.

Additional information about design of technical systems: No further data; see item 7.
· Components with limit values that require monitoring at the workplace:
The product does not contain any relevant quantities of materials with critical values that have to be
monitored at the workplace.
· Additional information: The lists that were valid during the creation were used as basis.
· Personal protective equipment:
· General protective and hygienic measures:
Keep away from foodstuffs, beverages and feed.
Immediately remove all soiled and contaminated clothing.
Wash hands before breaks and at the end of work.
Avoid contact with the eyes and skin.
· Breathing equipment:
In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure
use respiratory protective device that is independent of circulating air.
· Protection of hands:
Protective gloves
The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/
the chemical mixture.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the
degradation
· Material of gloves
The selection of the suitable gloves does not only depend on the material, but also on further marks of quality
and varies from manufacturer to manufacturer. As the product is a preparation of several substances, the
resistance of the glove material can not be calculated in advance and has therefore to be checked prior to theTrade name: TOILET BOWL CLEANER(LEMON)
(Contd. of page 3)
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application.
· Penetration time of glove material
The exact break through time has to be found out by the manufacturer of the protective gloves and has to be
observed.
· Eye protection:
Tightly sealed goggles
· Body protection:
Mixers, loaders, and others exposed to methylisothiazolinone products must wear:
– long-sleeve shirt and long pants
-chemical-resistant gloves
– shoes plus socks.
-Chemical-resistant apron
Discard clothing or other absorbent materials that have been drenched or heavily contaminated with this
product’s concentrate. Do not reuse them. Follow manufacturer’s instructions for cleaning/maintaining
PPE.
If no such instructions for washables exist, use detergent and hot water. Keep and wash PPE separately from
other laundry.
Users should wash hands before eating, drinking, chewing gum, using tobacco, or using the toilet.”
“Users should remove clothing immediately if pesticide gets inside. Them wash thoroughly and put on clean
clothing.”
“Users should remove PPE immediately after handling this product. Wash the outside of gloves before
removing. As soon as possible, wash thoroughly.

General Information
Form: Solid
Color: White
Odor: Lemon
· Change in condition
Melting point/Melting range: Not available
Boiling point/Boiling range: Not available
· Flash point: Not available
· Flammability (solid, gaseous): Not available
· Ignition temperature: Not available
· Auto igniting: Product is not selfigniting.
· Danger of explosion: Product is not explosive. However, formation of explosive air/vapor mixtures
are possible.
· Explosion limits:
Lower: Not available
Upper: Not available
· Oxidizing properties Not available
· Vapor pressure: Not available
· Density: Not available
· Relative density Not available
· Vapour density Not available
· Evaporation rate Not available

11 Toxicological information
· Acute toxicity:
· LD/LC50 values that are relevant for classification:
497-19-8 sodium carbonate
Oral LD50 4090 mg/kg (rat)
5949-29-1 citric acid monohydrate
Oral LD50 5040 mg/kg (mouse)
124-13-0 octanal
Oral LD50 5630 mg/kg (rat)
Dermal LD50 6350 mg/kg (rabbit)
112-31-2 decanal
Oral LD50 3730 mg/kg (rat)
Dermal LD50 5040 mg/kg (rabbit)
5392-40-5 Citral
Oral LD50 4960 mg/kg (rat)
78-70-6 Linalool
Oral LD50 2790 mg/kg (rat)
Dermal LD50 5610 mg/kg (rabbit)
15356-70-4 D-menthol
Oral LD50 2900 mg/kg (rat)
Dermal LD50 >5000 mg/kg (rabbit)
105-54-4 ethyl butyrate
Oral LD50 13000 mg/kg (rat)
· Primary irritant effect:
· on the skin: Caustic effect on skin and mucous membranes.
· on the eye: Strong caustic effect.
· Sensitization: Sensitization possible through skin contact.
· Additional toxicological information:
The product shows the following dangers according to internally approved calculation methods for
preparations:
Harmful
Corrosive

12 Ecological information
· Remark: Toxic for fish
· General notes:
Water hazard class 3 (Self-assessment): extremely hazardous for water
Do not allow product to reach ground water, water course or sewage system, even in small quantities.
Must not reach bodies of water or drainage ditch undiluted or unneutralized.
Danger to drinking water if even extremely small quantities leak into the ground.
Also poisonous for fish and plankton in water bodies.
Toxic for aquatic organisms

13 Disposal considerations
· Product:
· Recommendation:
Must not be disposed of together with household garbage. Do not allow product to reach sewage system.
· Waste disposal key:
Methylisothiazolinone is toxic to terrestrial and aquatic plants, fish and aquatic invertebrates. Do not
discharge effluent containing this product into lakes, streams, ponds estuaries, oceans or other waters unless
in accordance with the requirements of a National Pollutant Discharge Elimination System (NPDES) permit
and the permitting authority has been notified in writing prior to discharge. Do not discharge effluent
containing this product to sewer systems without previously notifying the local sewage treatment plant
authority. For guidance contact your state Water Board or Regional Office of the EPA.
· Uncleaned packagings:
· Recommendation: Disposal must be made according to official regulations.

15 Regulations
· Sara
· Section 355 (extremely hazardous substances):
None of the ingredients is listed.
· Section 313 (Specific toxic chemical listings):
None of the ingredients is listed.
· TSCA (Toxic Substances Control Act):
All ingredients are listed.
· Proposition 65
· Chemicals known to cause cancer:
None of the ingredients is listed.
· Chemicals known to cause reproductive toxicity for females:
None of the ingredients is listed.
· Chemicals known to cause reproductive toxicity for males:
None of the ingredients is listed.
· Chemicals known to cause developmental toxicity:
None of the ingredients is listed.
· Cancerogenity categories
· EPA (Environmental Protection Agency)
None of the ingredients is listed.

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· IARC (International Agency for Research on Cancer)
None of the ingredients is listed.
· NTP (National Toxicology Program)
None of the ingredients is listed.
· TLV (Threshold Limit Value established by ACGIH)
None of the ingredients is listed.
· NIOSH-Ca (National Institute for Occupational Safety and Health)
None of the ingredients is listed.
· OSHA-Ca (Occupational Safety & Health Administration)
None of the ingredients is listed.
· Product related hazard informations:
The product has been classified and marked in accordance with directives on hazardous materials.
· Hazard symbols:
Corrosive
Dangerous for the environment
· Hazard-determining components of labelling:
5-chloro-2-methyl-2H-isothiazol-3-one
· Risk phrases:
Harmful by inhalation, in contact with skin and if swallowed.
Danger of cumulative effects.
Causes burns.
Irritating to respiratory system.
May cause sensitisation by skin contact.
Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
· Safety phrases:
Keep locked up and out of the reach of children.
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
Do not empty into drains, dispose of this material and its container at hazardous or special waste collection
point.
Wear suitable protective clothing, gloves and eye/face protection.
In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).

The contents and format of this MSDS/SDS are in accordance with 29 CFR 1910.1200(g)
DISCLAIMER OF LIABILITY
The information in this MSDS/SDS was obtained from sources which we believe are reliable. However, the
information is provided without any warranty, express or implied, regarding its correctness. The conditions
or methods of handling, storage, use or disposal of the product are beyond our control and may be beyond
our knowledge. For this and other reasons, we do not assume responsibility and expressly disclaim liability
for loss, damage or expense arising out of or in anyway connected with the handling, storage, use or disposal
of the product. This MSDS/SDS was prepared and is to be used only for this product. If the product is used as
a component in another product, this MSDS/SDS information may not be applicable.
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